Here are a number of posts about the Arduino esp8266 and MQTT.
ESP8266: Connecting to MQTT brokerHow To Use Basic MQTT on ArduinoHow to use ArduinoJson with PubSubClientCallback function and MQTT Arduino clientStrings, bytes, char arrays MQTT arghghWhat is the best MQTT Client for Pub and Sub?
On a related note - this discusses converting byte* to char[]
Is it possible to convert a byte* to char[]?convert byte array into string
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